N-环烷基-3-烯基苯甲酰基吡唑衍生物制造技术

本发明专利技术涉及式Ⅰ的环烷基取代的苯甲酰基吡唑，其中可变基团，例如，为下述定义：Ｒ↑［１］是氢，硝基，卤素，氰基，氰硫基，或未取代的或取代的脂族基团；Ｒ↑［２］未取代的或取代的脂族基团，卤素，硝基，或取代的磺酰基或氨基，Ｒ↑［３］是氢，卤素，Ｃ↓［１］－Ｃ↓［６］－烷基，Ｃ↓［１］－Ｃ↓［６］－卤代烷基，Ｃ↓［１］－Ｃ↓［６］－烷氧基，Ｃ↓［２］－Ｃ↓［６］－烯基或Ｃ↓［２］－Ｃ↓［６］－炔基；Ｒ↑［４］，Ｒ↑［５］是氢，硝基，卤素，氰基，氰硫基，未取代的或取代的脂族基团或取代的磺酰基或氨基，Ｒ↑［６］是氢，卤素，Ｃ↓［１］－Ｃ↓［６］－烷基，Ｃ↓［１］－Ｃ↓［６］－烷氧基，Ｃ↓［３］－Ｃ↓［８］－环烷基；Ｒ↑［７］具有３－１４个环原子的环系；Ｒ↑［１６］是羟基或取代的羟基；以及它们的互变异构体或农业上应用的盐。而且，本发明专利技术涉及式Ⅰ化合物的制备方法，含有它们的组合物，以及式Ⅰ化合物和含有该化合物的组合物控制有害植物的用途。（*该技术在2020年保护过期，可自由使用*）

N- based -3- alkenyl benzoyl pyrazole derivatives

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【技术实现步骤摘要】
本专利技术涉及式I的环烷基取代的苯甲酰基吡唑 其中R1是氢，硝基，卤素，氰基，氰硫基，C1-C6-烷基，C1-C6-卤代烷基，C1-C6-烷氧基，C1-C6-烷硫基，C1-C6-烷氧基-C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，-S(O)nR8，-SO2OR9，-SO2NR9R10，-NR10SO2R11，-NR10COR11，-PO(OR12)(OR13)；R2是氢，C1-C6-烷基，C1-C6-烷氧基，C1-C6-烷硫基，C2-C6-烯基，C2-C6-炔基，卤素，硝基，-S(O)nR8，-SO2OR9，-SO2NR9R10，-NR10SO2R11，-NR10COR11，-PO(OR12)(OR13)；R3是氢，卤素，C1-C6-烷基，C1-C6-卤代烷基，C1-C6-烷氧基，C2-C6-烯基或C2-C6-炔基；R4，R5是氢，硝基，卤素，氰基，氰硫基，C1-C6-烷基，C1-C6-卤代烷基，C3-C6-环烷基，C2-C6烷基，C4-C6-环烯基，C2-C6-炔基，C1-C6-烷硫基，C1-C6-卤代烷氧基，-COR12，-CO2R12，-COSR12，-CONR12R1本文档来自技高网...

【技术保护点】
式Ⅰ的吡唑＊＊＊ Ⅰ其中：Ｒ↑［１］ 是氢，硝基，卤素，氰基，氰硫基，Ｃ↓［１］－Ｃ↓［６］－烷基，Ｃ↓［１］－Ｃ↓［６］－卤代烷基，Ｃ↓［１］－Ｃ↓［６］－烷氧基，Ｃ↓［１］－Ｃ↓［６］－烷硫基，Ｃ↓［１］－Ｃ↓［６］－烷氧基 －Ｃ↓［１］－Ｃ↓［６］－烷基，Ｃ↓［２］－Ｃ↓［６］－烯基，Ｃ↓［２］－Ｃ↓［６］－炔基，－Ｓ（Ｏ）↓［ｎ］Ｒ↑［８］，－ＳＯ↓［２］ＯＲ↑［９］，－ＳＯ↓［２］ＮＲ↑［９］Ｒ↑［１０］，－ＮＲ↑［１０］ＳＯ↓［２］Ｒ↑［１１］，－ＮＲ↑［１０］ＣＯＲ↑［１１］，－ＰＯ（ＯＲ↑［１２］）（ＯＲ↑［１３］）；Ｒ↑［２］ 是氢，Ｃ↓［１］－Ｃ...

【技术特征摘要】
DE 1999-7-9 19931863.81.式I的吡唑 其中R1是氢，硝基，卤素，氰基，氰硫基，C1-C6-烷基，C1-C6-卤代烷基，C1-C6-烷氧基，C1-C6-烷硫基，C1-C6-烷氧基-C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，-S(O)nR8，-SO2OR9，-SO2NR9R10，-NR10SO2R11，-NR10COR11，-PO(OR12)(OR13)；R2是氢，C1-C6-烷基，C1-C6-烷氧基，C1-C6-烷硫基，C2-C6-烯基，C2-C6-炔基，卤素，硝基，-S(O)nR8，-SO2OR9，-SO2NR9R10，-NR10SO2R11，-NR10COR11，PO(OR12)(OR13)；R3是氢，卤素，C1-C6-基，C1-C6-卤代烷基，C1-C6-烷氧基，C2-C6-烯基或C2-C6-炔基；R4，R5是氢，硝基，卤素，氰基，氰硫基，C1-C6-烷基，C1-C6-卤代烷基，C3-C6-环烷基，C2-C6-烯基，C4-C6-环烯基，C2-C6-炔基，C1-C6-烷硫基，C1-C6-卤代烷氧基，-COR12，-CO2R12，-COSR12，-CONR12R13，-C(R14)＝NR15，-PO(OR12)(OR13)，带有下述基团的C1-C4-烷基，其中所述基团是-COR12，-CO2R12，-COSR12，-CONR12R13或-C(R14)＝NR15；杂环基，杂环基-C1-C4-烷基，苯基，苯基-C1-C4-烷基，杂芳基或杂芳基-C1-C4-烷基，其中最后所述的六个基团可以被取代；或R4和R5一起形成C2-C6-烷二基链，该链可被C1-C4-烷基一-至四取代和/或被氧或硫或未取代的或C1-C4-烷基取代的氮所间断；R6是氢，卤素，C1-C6-烷基，C1-C6-烷氧基，C3-C8-环烷基；R7是具有3-14个环原子的环系，该环系可以是未取代的或被C1-C6-烷基，C1-C6-烷氧基，C1-C6-卤代烷基，C1-C6-卤代烷氧基，卤素取代；或是被环系取代的C1-C6-烷基；n 是0，1或2；R8是C1-C6-烷基，C1-C6-卤代烷基，C1-C6-烷氧基-C2-C6-烷基，C3-C6-烯基或C3-C6-炔基；R9是氢，C1-C6-烷基，C1-C6-卤代烷基，C1-C6-烷氧基-C2-C6-烷基，C3-C6-烯基或C3-C6-炔基；R10是氢或C1-C6-烷基；R11是C1-C6-烷基或C1-C6-卤代烷基；R12是氢，C1-C6-烷基，C3-C6-环烷基，C1-C6-卤代烷基，C3-C6-烯基，C3-C6-炔基，苯基或苄基，其中最后所述的两个基团可被部分或全部卤代和/或带有一至三个下述基团硝基，氰基，C1-C4-烷基，C1-C4-卤代烷基，C1-C4-烷氧基，C1-C4-卤代烷氧基，C1-C4-烷基羰基或C1-C4-烷氧基羰基；R13是氢，C1-C6-烷基，C3-C6-基或C3-C6-炔基；或R12和R13一起形成C2-C6-烷二基链，该链可被C1-C4-烷基一-至四取代和/或被氧或硫或未取代的或C1-C4-烷基取代的氮所间断；R14是氢，C1-C6-烷基，C1-C6-卤代烷基，C1...

【专利技术属性】
技术研发人员：U尼德雷恩，N高兹，E鲍曼，W冯迪恩，S库迪斯，R高兹，K兰吉曼，G梅尔，U米斯利兹，M维茨切尔，M奥顿，KO维斯特法兰，H沃尔特，
申请(专利权)人：巴斯福股份公司，
类型：发明
国别省市：DE[德国]