取代的3-苯基吡唑制造技术

＊＊＊ Ⅰ 取代的３－苯基吡唑Ⅰ。其中Ｒ↑［１］＝Ｃ（Ｒ↑［８］）＝Ｃ（Ｒ↑［７］，Ｒ↑［１２］），－＊＊＊（Ｒ↑［７］，Ｒ↑［１２］），－Ｃ（Ｒ↑［９］，Ｒ↑［１０］）－Ｃ（Ｒ↑［８］，Ｒ↑［１１］，Ｒ↑［１２］），－Ｃ（Ｒ↑［９］）＝＊＊＊，－Ｃ（Ｒ↑［９］，Ｒ↑［１０］）－Ｃ（Ｒ↑［９］，Ｒ↑［１０］）－＊＊＊，－（Ｒ↑［９］）＝Ｃ（Ｒ↑［８］）－苯基或－Ｃ（Ｒ↑［９］，Ｒ↑［１０］）－Ｃ（Ｒ↑［８］，Ｒ↑［１３］）－苯基；Ｒ↑［２］＝氰基，三氟甲基或卤素；Ｒ↑［３］＝氢，Ｃ↓［１］－Ｃ↓［４］烷基，Ｃ↓［１］－Ｃ↓［４］卤代烷基或Ｃ↓［１］－Ｃ↓［４］烷氧基－Ｃ↓［１］－Ｃ↓［４］烷基；Ｒ↑［４］＝Ｃ↓［１］－Ｃ↓［４］烷氧基，Ｃ↓［１］－Ｃ↓［４］卤代烷氧基，Ｃ↓［１］－Ｃ↓［４］烷硫基，Ｃ↓［１］－Ｃ↓［４］卤代烷硫基，Ｃ↓［１］－Ｃ↓［４］烷基亚磺酰基，Ｃ↓［１］－Ｃ↓［４］卤代烷基亚磺酰基，Ｃ↓［１］－Ｃ↓［４］烷基磺酰基，或Ｃ↓［１］－Ｃ↓［４］卤代烷基磺酰基；Ｒ↑［５］＝氢，硝基，卤素，羧酸／羧酸酯基团，取代的或未取代的氨基羰基；Ｒ↑［６］＝氢或卤素；Ｙ＝－Ｏ－，－Ｓ－，－ＣＨ↓［２］－；Ｚ＝２－至５－员链；Ｒ↑［７］＝氰基，卤素，Ｃ↓［１］－Ｃ↓［４］烷基，Ｃ↓［１］－Ｃ↓［４］卤代烷基，Ｃ↓［２］－Ｃ↓［４］链烯基，羧酸／羧酸酯基团，取代的或未取代的氨基羰基；Ｒ↑［８］，Ｒ↑［９］，Ｒ↑［１０］，Ｒ↑［１３］＝氢，氰基，卤素，Ｃ↓［１］－Ｃ↓［４］烷基，Ｃ↓［１］－Ｃ↓［４］卤代烷基，Ｃ↓［２］－Ｃ↓［４］链烯基，羧酸／羧酸酯基团，取代的或未取代的－Ｎ（Ｈ）－ＣＯ－Ｒ↑［２５］，氨基或氨基羧基；Ｒ↑［１１］＝氰基，卤素，羧酸／羧酸酯基团，取代的或未取代的氨基或氨基羰基，叠氮基，羟基，（卤代）烷氧基，链烯氧基或烷基羰氧基；Ｒ↑［１２］是异＊唑烷基羰基，羧酸／羧酸酯基团，酰胺基团，－ＣＯ－Ｏ－Ｎ＝Ｃ（Ｒ↑［３１］）－（Ｃ↓［１］－Ｃ↓［６］烷基），－ＣＯ－Ｏ－Ｎ＝Ｃ（Ｒ↑［３１］）－ＣＯ－Ｏ－（Ｃ↓［１］－Ｃ↓［６］烷基），－ＣＯ－Ｏ－Ｎ＝Ｃ（Ｒ↑［３１］）－（Ｃ↓［１］－Ｃ↓［４］烷基），－ＣＯ－Ｏ－（Ｃ↓［１］－Ｃ↓［４］烷基），－ＣＯ－Ｏ－ＣＨ↓［２］Ｒ↑［１４］，－ＣＯ－Ｏ－Ｃ（Ｒ↑［１４］）－（Ｃ↓［１］－Ｃ↓［４］烷基），取代的或未取代的氨基羰基或氨基硫代羰基，－ＣＯ－ＮＨ－Ｓ（*该技术在2015年保护过期，可自由使用*）

Substituted 3- phenyl pyrazole

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【技术实现步骤摘要】

本专利技术涉及式I的新型取代的3-苯基吡唑 其中R1是-C(R8)＝C(R7，R12)， -C(R9，R10)-C(R8，R11，R12)， ，-(R9)＝C(R8)-苯基或-C(R9，R10)-C(R8，R13)-苯基，其中如果需要的话每个苯环可以带一至三个选自硝基，氰基，氟，氯，溴，三氟甲基，羟基，羟基羰基，C1-C4烷氧基以及C1-C4烷氧基羰基的取代基；R2是氰基，三氟甲基或卤素；R3是氢，C1-C4烷基，C1-C4卤代烷基或C1-C4烷氧基C1-C4烷基；R4是C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基，C1-C4卤代烷硫基，C1-C4烷基亚磺酰基，C1-C4卤代烷基亚磺酰基，C1-C4烷基磺酰基，或C1-C4卤代烷基磺酰基；R5是氢，硝基，卤素，-COOR15或-CO-N(R16，R17)；R6是氢或卤素；Y是氧，硫或亚甲基；Z是一个含二至五个亚甲基单元的链以及，如果需要的话含一个或二个以下基团-O-，-S-，-CS-，-CO-或-CH(C1-C4烷基)-或-N(R14)-，其中R14是氢，C1-C4烷基，苯基或苄基；R7是氰基，卤素，C1-C4烷基，本文档来自技高网...

【技术保护点】
一种式Ⅰ的取代的３－苯基吡唑＊＊＊ Ⅰ其中Ｒ↑［１］是－Ｃ（Ｒ↑［８］）＝Ｃ（Ｒ↑［７］，Ｒ↑［１２］），＊＊＊，－Ｃ（Ｒ↑［９］，Ｒ↑［１０］）－Ｃ（Ｒ↑［８］，Ｒ↑［１１］，Ｒ↑［１２］），＊＊＊，－（Ｒ↑［９］）＝Ｃ（Ｒ↑ ［８］）－苯基或－Ｃ（Ｒ↑［９］，Ｒ↑［１０］）－Ｃ（Ｒ↑［８］，Ｒ↑［１３］）－苯基，其中如果需要的话每个苯环可以带一至三个选自硝基，氰基，氟，氯，溴，三氟甲基，羟基，羟基羰基，Ｃ↓［１］－Ｃ↓［４］烷氧基以及Ｃ↓［１］－Ｃ↓［４］烷氧基羰基的取代基；Ｒ↑［２］是氰基，三氟甲基或卤素；Ｒ↑［３］是氢，Ｃ↓［１］－Ｃ↓［４］烷基，Ｃ↓［１］－Ｃ...

【技术特征摘要】
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【专利技术属性】
技术研发人员：CS旺戴布施哈尼费尔德，R克林兹，G哈姆普里特，E海斯特拉彻尔，P莎夫尔，K狄特里奇，KO怀斯特法兰，M吉尔布尔，H瓦尔特，
申请(专利权)人：巴斯福股份公司，
类型：发明
国别省市：DE[德国]