新的噻吩磺脲衍生物及其除草组合物制造技术

一种下列通式（Ⅰ）表示的噻吩磺酰脲衍生物及其盐： ＊＊＊ （Ⅰ） 其中 Ｔ表示具有下列通式的Ｔ１，Ｔ２，或Ｔ３基团： ＊＊＊ Ｔ１ ＊＊＊ Ｔ２ ＊＊＊ Ｔ３ 其中 Ｅ表示直键； Ｒ表示氢或Ｃ↓［１－４］酰基； Ｒ↑［１］表示由１到３个卤原子取代的Ｃ↓［１－６］烷基； Ｒ↑［２］表示氢，Ｃ↓［１－３］烷基，Ｃ↓［－１３］卤代烷基，卤素氰基，Ｃ↓［１－３］烷氧基，Ｃ↓［１－３］卤代烷氧基，氨基，甲氨基，二甲氨基，或用Ｃ↓［１－２］烷氧基、Ｃ↓［１－２］卤代烷氧基、硫羟基、甲硫基、氰基或羟基取代的Ｃ↓［１－２］烷基； Ａ表示选自具有下列通式的Ａ１到Ａ４基团： ＊＊＊ （Ａ１） ＊＊＊ （Ａ２） ＊＊＊ （Ａ３） ＊＊＊ （Ａ４） 其中 Ｘ表示氢，Ｃ↓［１－４］烷基，Ｃ↓［１－４］烷氧基，Ｃ↓［１－４］卤代烷基，Ｃ↓［１－４］卤代烷氧基，Ｃ↓［１－４］烷硫基，Ｃ↓［１－４］卤代烷硫基，卤素，Ｃ↓［２－５］烷氧烷基，Ｃ↓［２－５］烷氧烷氧基，亚氨基，Ｃ↓［１－３］烷氨基，双（Ｃ↓［１－３］烷基）氨基或Ｃ↓［３－５］环烷基； Ｘ↑［１］表示Ｃ↓［１－２］烷基，Ｃ↓［１－２］烷氧基或Ｃ↓［１－２］烷硫基； Ｙ表示氢，Ｃ↓［１－４］烷基，Ｃ↓［１－４］烷氧基，Ｃ↓［１－４］卤代烷氧基，Ｃ↓［１－４］卤代烷硫基，Ｃ↓［１－４］烷硫基，Ｃ↓［２－５］烷氧烷基，Ｃ↓［２－５］烷氧烷氧基，氨基，Ｃ↓［１－３］烷氨基，双（Ｃ↓［１－３］烷基）氨基，Ｃ↓［３－４］链烯氧基，Ｃ↓［３－４］炔氧基，Ｃ↓［２－５］烷硫烷基，Ｃ↓［１－４］卤代烷基，Ｃ↓［２－４］炔基，叠氮基，氰基，Ｃ↓［２－５］烷基亚磺酰烷基，Ｃ↓［２－５］烷基磺酰烷基，羟甲基，Ｃ↓［３－５］环烷基或Ｃ↓［３－５］环烷氧基； Ｙ↑［１］表示氧或亚甲基； Ｙ↑［２］表示氢或甲基；以及 Ｚ表示Ｎ或ＣＨ； 条件是（１）当Ｘ为氟，氯，碘时，Ｚ表示ＣＨ而Ｙ表示甲氟基，乙氧基，甲氧基甲氨基，氨基，甲氨基，二甲氨基或二氟甲氟基以及 （２）当Ｘ或Ｙ为二氟甲氰基时，Ｚ表示ＣＨ以及 （３）当Ｘ和Ｙ的总的碳原子数为４或４以上时，Ｒ↑［２］表示具有至多４个碳原子的基团。（*该技术在2014年保护过期，可自由使用*）

Novel thiophene derivatives and herbicidal compositions thereof

One of the following general formula (I) said the thiophenesulfonylurea derivatives and salts thereof: * * * (I) has the following general formula wherein T represents T1, T2 or T3 groups: * * * T1 * * * T2 * * * T3 E said straight key; R represents hydrogen or C: 1 - 4 acyl R = 1; the replaced by 1 to 3 halogen atoms C 1 - 6 lower alkyl; R = 2: 1 C represents hydrogen, alkyl - 3, C - 13: \halogenated alkyl, halogen cyano group, C: 1 - 3 alkoxy, C: 1 - 3 halogenated alkoxy, amino, methyl amino, two methylamino, or C: 1 - 2 alkoxy, C: 1 - 2 halogenated alkoxy, sulfur, hydroxy methylthio, cyano or hydroxy substituted \u7684\uff23\u2193\uff3b\uff11\uff0d\uff12\uff3d\u70f7\u57fa\uff1b \uff21\u8868\u793a\u9009\u81ea\u5177\u6709\u4e0b\u5217\u901a\u5f0f\u7684\uff21\uff11\u5230\uff21\uff14\u57fa\u56e2\uff1a \uff0a\uff0a\uff0a \uff08\uff21\uff11\uff09 \uff0a\uff0a\uff0a \uff08\uff21\uff12\uff09 \uff0a\uff0a\uff0a \uff08\uff21\uff13\uff09 \uff0a\uff0a\uff0a \uff08\uff21\uff14\uff09 \u5176\u4e2d \uff38\u8868\u793a\u6c22\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u70f7\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u70f7\u6c27\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u5364\u4ee3\u70f7\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u5364\u4ee3\u70f7\u6c27\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u70f7\u786b\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u5364\u4ee3\u70f7\u786b\u57fa\uff0c\u5364\u7d20\uff0c\uff23\u2193\uff3b\uff12\uff0d\uff15\uff3d\u70f7\u6c27\u70f7\u57fa\uff0c\uff23\u2193\uff3b\uff12\uff0d\uff15\uff3d\u70f7\u6c27\u70f7\u6c27\u57fa\uff0c\u4e9a\u6c28\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff13\uff3d\u70f7\u6c28\u57fa\uff0c\u53cc\uff08\uff23\u2193\uff3b\uff11\uff0d\uff13\uff3d\u70f7\u57fa\uff09\u6c28\u57fa\u6216\uff23\u2193\uff3b\uff13\uff0d\uff15\uff3d\u73af\u70f7\u57fa\uff1b \uff38\u2191\uff3b\uff11\uff3d\u8868\u793a\uff23\u2193\uff3b\uff11\uff0d\uff12\uff3d\u70f7\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff12\uff3d\u70f7\u6c27\u57fa\u6216\uff23\u2193\uff3b\uff11\uff0d \uff12\uff3d\u70f7\u786b\u57fa\uff1b \uff39\u8868\u793a\u6c22\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u70f7\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u70f7\u6c27\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u5364\u4ee3\u70f7\u6c27\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u5364\u4ee3\u70f7\u786b\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u70f7\u786b\u57fa\uff0c\uff23\u2193\uff3b\uff12\uff0d\uff15\uff3d\u70f7\u6c27\u70f7\u57fa\uff0c\uff23\u2193\uff3b\uff12\uff0d\uff15\uff3d\u70f7\u6c27\u70f7\u6c27\u57fa\uff0c\u6c28\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff13\uff3d\u70f7\u6c28\u57fa\uff0c\u53cc\uff08\uff23\u2193\uff3b\uff11\uff0d\uff13\uff3d\u70f7\u57fa\uff09\u6c28\u57fa\uff0c\uff23\u2193\uff3b\uff13\uff0d\uff14\uff3d\u94fe\u70ef\u6c27\u57fa\uff0c\uff23\u2193\uff3b\uff13\uff0d\uff14\uff3d\u7094\u6c27\u57fa\uff0c\uff23\u2193\uff3b\uff12\uff0d\uff15\uff3d\u70f7\u786b\u70f7\u57fa\uff0c\uff23\u2193\uff3b\uff11\uff0d\uff14\uff3d\u5364\u4ee3\u70f7\u57fa\uff0c\uff23\u2193\uff3b\uff12\uff0d\uff14\uff3d\u7094\u57fa\uff0c\u53e0\u6c2e\u57fa\uff0c\u6c30\u57fa\uff0c\uff23\u2193\uff3b\uff12\uff0d\uff15\uff3d\u70f7\u57fa\u4e9a\u78fa\u9170\u70f7\u57fa\uff0c\uff23\u2193\uff3b\uff12\uff0d\uff15\uff3d\u70f7\u57fa\u78fa\u9170\u70f7\u57fa\uff0c\u7f9f\u7532\u57fa\uff0c\uff23\u2193\uff3b\uff13\uff0d\uff15\uff3d\u73af\u70f7\u57fa\u6216\uff23\u2193\uff3b\uff13\uff0d\uff15\uff3d\u73af\u70f7\u6c27\u57fa\uff1b \uff39\u2191\uff3b\uff11 Said: oxygen or methylene; Y = 2 represents hydrogen or methyl; and Z represents N or CH; the condition is (1) when X is fluorine, chlorine, iodine, Z said CH Y said a fluorine based, ethoxy methoxy, methyl amino, amino, methyl amino, two dimethylamino or two fluorine methyl fluoride based and (2) when X or Y is a cyano two fluorine, said Z CH, (3) when the total number of carbon atoms of X and Y for more than 4 or 4, R = 2 with up to 4 carbon atoms groups.

【技术实现步骤摘要】

本专利技术涉及由下列通式(1)表示的新的噻吩磺酰脲衍生物及其盐 其中T表示具有下列通式的T1，T2，成T3基团 其中E表示直键；R表示氢或C1-4酰基；R1表示用1到3个卤原子取代的C1-6烷基；R2表示氢，C1-3烷基，C1-3卤代烷基，卤素，氰基，C1-3烷氧基，C1-3卤代烷氧基，氨基，甲氨基，二甲氨基，或用C1-2烷氧基、C1-2卤代烷氧基、硫羟基、甲硫基、氰基或羟基取代的C1-2烷基；A表示选自具有下列通式的A1到A4基团 其中X表示氢，C1-4烷基，C1-4烷氧基，C1-4卤代烷基，C1-4卤代烷氧基，C1-4烷硫基，C1-4卤代烷硫基，卤素，C2-5烷氧烷基，C2-5烷氧烷氧基，亚氨基，C1-3烷氧基，双(C1-3烷基)氨基或C3-5环烷基；X1表示C1-2烷基，C1-2烷氧基或C1-2烷硫基；Y表示氢，C1-4烷基，C1-4烷氧基，C1-4卤代烷氧基，C1-4卤代烷硫基，C1-4烷硫基，C2-5烷氧烷基，C2-5烷氧烷氧基，氨基，C1-3烷氨基，双(C1-3烷基)氨基，C3-4链烯氧基，C3-4炔氧基，C2-5烷硫烷基，C1-4卤代烷基，C2-4炔基，叠氮基，氰本文档来自技高网...

【技术保护点】

【技术特征摘要】

【专利技术属性】
技术研发人员：金大璜，尹璟烈，柳在旭，李连洙，姜升圭，黄仁泽，
申请(专利权)人：韩国化学研究所，
类型：发明
国别省市：